Ce-Uio-66，CAS#: 1801427-51-9

资料明称：UIO-66(Ce)

许多简称：Ce-UIO-66-BDC

CAS：1801427-51-9

方氧化学式C48H24O32Ce6

政府部门团伙量1953.38

配位合金材料Ce

配体    对苯二甲酸（CAS：100-21-0）

孔的直径     0.8nm, 1.1nm

孔容     0.5 cm3/g

比表面上BET比漆层1100 m2/g

服务形貌    淡黄绿色粉末状原材料  

粒度分布      50-200nm 不玩法科粒

用期刊论文：

三公开打了个种生产-黑色金属框架结构涂料Ce-UiO-66在分解氯代芳烃类耐久性巧妙影响物(POPs)中的APP。MOF素材享有大比从表面积和多孔物理性质，可对于承载担载彩石酚类化合物，提升了彩石的增溶度，所以有益于于提升促使剂的几丁质酶。主几丁质酶酚类化合物为Ce,催化反应剂的比面积为1000-1200m2/g，微孔过滤构造。设计黑色金属整体布局完成后材质Ce-UiO-66可不可以地温催化氧化分解氯代芳烃类POPs。

We synthesized a CuO/CeO2 catalyst using a copper ions encapsulated ceria metal-organic framework (MOF) Ce-UiO-66 as the precursor. The CuO/CeO2 catalysts derived by calcining the MOF precursor (the x-CuCe catalysts) showed the better activity and selectivity for the preferential CO oxidation in the H2-rich stream than the CuO/CeO2 catalyst prepared by wetness impregnation (CuCe-im). A temperature window to match the CO conversion and O2 to CO2 selectivity higher than 99.5% at the same time appeared using the x-CuCe catalysts as the catalyst. Raman and XPS results indicated that more oxygen vacancies were formed in the bulk of ceria in the x-CuCe catalysts than that in the CuCe-im catalyst, which could promote the mobility of oxygen. Our results indicated that the surface lattice oxygen and the oxygen vacancies in the bulk of ceria could enhance the catalytic performance of the CuO/CeO2 catalysts.

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