NO2-UIO-66,UIO-66-NO2
CAS NO.:1260119-01-4
碳原子式:C48H22N6O44Zr6
团伙量:1934.05
产品英文名称:NO2-UIO-66
同一称谓:UIO-66-NO2
CAS:1260119-01-4
材料设计眼镜框架 NO2-UIO-66,UIO-66-NO2,CAS: 1260119-01-4 的结构设计式
单位名称分子结构式 C48H18N6O44Zr6
标准分子式量 1930.01
配位金属质 Zr 配体 2-硝基对苯二甲酸(CAS:610-29-7)
管径 0.8nm, 1.1nm 孔容 0.5 cm3/g
比面 BET比面600-800 m2/g
金属有机框架 NO2-UIO-66,UIO-66-NO2,CAS: 1260119-01-4 的产品性状
厂品形貌 黑色金属粉
White Powder
孔径 100nm的样子不要求奈米颗粒状
金属有机框架 NO2-UIO-66,UIO-66-NO2,CAS: 1260119-01-4 的稳定性
1) NO2-UIO-66 比较稳固,在水悬浊液和强酸必备条件下比较稳固。UIO-66是日子比较稳固性好的MOF的一个,都可以太久比较稳固储藏。
存有和纯化步骤
1) 烘干或温度过低要求下,烘干胶封保存图片
2) 小编建议便用前150度(真空泵)烘干箱活性3小时候
另外因素
荧光:NA
金属有机框架 NO2-UIO-66,UIO-66-NO2,CAS: 1260119-01-4 的应用领域
1) 储气建筑板材和离心分离建筑板材
2) UIO-66的刚需节构是催化反应剂各种载体
期刊论文:
Metal organic frameworks (MOFs), UiO-66-NO2 and UiO-66-NO2-N (N = -NH2, -(OH)2, -COOH)2), were synthesized under solvothemal conditions using different functionalized organic linkers. The synthesized samples were further activated by solvent exchange using methanol and chloroform. All samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and N2 adsorption/desorption. Gas adsorption of CO2 and N2 on all samples has been evaluated at 760 mmHg and different temperatures. It was found that UiO-66-NO2-NH2 by methanol or chloroform activation presented much higher CO2 adsorption than other samples and the adsorption capacities are around (87 and 74) cm3·g-1 on chloroform-activated and methanol-activated samples, respectively, at 273 K and 760 mmHg.
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